Complexometric determination of thallium(III) using ethanethiol as a selective masking agent
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منابع مشابه
Complexometric Determination of Thallium(III) using Ethanethiol as a Selective Masking Agent
Um método complexométrico simples e seletivo é proposto para a determinação de tálio na presença de outros metais, pela habilidade do etanetiol em mascarar seletivamente íons tálio (III). Em solução, o tálio presente foi inicialmente complexado com um excesso conhecido de EDTA, sendo o excesso titulado com uma solução padrão de sulfato de zinco em pH 5-6 (hexamina), usando-se xilenol como indic...
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This paper describes a indirect complexometric method for the determination of mercury in the presence of co-ions, based on the selective masking ability of potassium iodide. To the mixture of mercury (II) and other metal ion solution, EDTA solution was added in excess of the metal ions present. The pH of the solution was adjusted to 5.0-6.0 using solid hexamine (10 ± 2 g) and surplus EDTA was ...
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BACKGROUND A complexometric method based on selective masking and de-masking has been developed for the rapid determination of aluminium, lead and zinc from the same solution in glass and glass frit samples. The determination is carried out using potassium cyanide to mask zinc, and excess disodium salt of EDTA to mask lead and aluminium. The excess EDTA was titrated with standard Mn(II)SO(4 )so...
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The extraction-separation of lanthanum and europium ions with bis(2-ethylhexyl) phosphoric acid (DEHPA) in cyclohexane was improved by adding 12-crown-4 (12C4) to the aqueous phase as a masking agent. In the presence of this crown ether the extraction curve of lanthanum ions versus pH shifts to the higher pH region, while the curve is not influenced for the europium ions. Consequently the s...
متن کاملComplexometric Determination of Hydroxyzinium Chloride
The conditions of preparation of hydroxyziniurn tetraiodocadmiatewere elaborated. The chemical composition and solubility were determined as well as thermal analysis was performed. Basi ng on the spectrophotometric investigations the mechanism of hydroxyziniumtetraiodocadmiate formation was established. The method of the complexometric determination of hydroxyzinium chloride, within the concent...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2006
ISSN: 0103-5053
DOI: 10.1590/s0103-50532006000200014